Hydrophobicity
Silicone rubber surfaces are hydrophobic — they repel water, so it beads into droplets instead of forming a continuous film. Since a continuous wet conductive film is a precondition for contamination flashover, keeping water as separated droplets interrupts the leakage path and reduces leakage current.
Hydrophobicity, in one idea
Hydrophobicity means water does not spread into a continuous film — it forms separated droplets. This is the key concept of the whole page: contamination flashover requires a conductive wet path along the surface, so if the water stays as separated droplets, leakage current is reduced and dry-band arcing is delayed.
Hydrophobicity transfer — why a polluted silicone surface still wins
Silicone rubber does not only repel water on a clean surface. Low-molecular-weight (LMW) silicone chains can migrate through or over the pollution layer and make the pollution surface partly hydrophobic. This hydrophobicity transfer is one of the main reasons silicone rubber keeps performing well under contaminated service conditions, where a porcelain surface would already have formed a conductive film.
Smaller diameter
Composite long-rods often have smaller diameters than station porcelain, which changes the surface current path and wetting behaviour and contributes to excellent contamination performance.
Shed shape
Shed material matters, but so does shed shape. The profile affects pollution accumulation, wetting, drainage, dry-band formation, arc development and self-cleaning — so composite performance is geometry-dependent as well as material-dependent.